$$ \ce{NO(g) + NO3(g) -> 2NO2(g)} $$
$$ \text{rate} = k[\ce{NO}][\ce{NO3}] $$
The reaction represented above occurs in a single step that involves the collision between a particle of \(\ce{NO}\) and a particle of \(\ce{NO3}\). A scientist correctly calculates the rate of collisions between \(\ce{NO}\) and \(\ce{NO3}\) that have sufficient energy to overcome the activation energy. The observed reaction rate is only a small fraction of the calculated collision rate. Which of the following best explains the discrepancy?