Going through the answer choices:
Glucose, \(\ce{C6H12O6}\), does not dissociate in solution. It does not form ions and therefore does not conduct electricity in any phase.
\(\ce{NaOH}\) will likely form an ionic solid.
In ionic solids, the ions fill the lattice points and are unable to move.
Ionic solids have a high melting point due to the attraction between charged ions. In solution, \(\ce{NaOH}\) will dissociate into ions and therefore conduct electricity.
\(\ce{SiO2}\) will form a network atomic solid.
Each silicon atom is connected to four oxygen atoms, forming a large network structure.
The melting point is extremely high due to these bonds. \(\ce{SiO2}\) does not conduct electricity
since it does not dissociate in water.
Copper has a high melting point as a metal. It does conduct electricity as a solid due to highly mobile free electrons.