At which of the following temperatures and pressures would a real gas be most likely to deviate from ideal behavior?

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Gasses deviate from ideal behavior at high pressures and low temperatures.

Typically, we can ignore the interactions between gas molecules and ignore the space gas molecules take up.

In a high pressure system (low volume container), the volume of the gases will no longer be negligible.

At low temperatures (lower velocity), gasses approach the condensation point and intermolecular forces play a larger role.